60%~62% Sodium Hydride CAS 7646-69-7 Nah

• Powder: Yes
• Customized: Non-Customized
• Certification: ISO 9001
• Model NO.: Sodium hydride
• Suitable for: Adult
• State: Solid
• Purity: 60%~62%
• Apearance: Silver Granulars
• Transport Package: Steel Drum
• Specification: 100kg or120kg drum
• Trademark: SAMREAL
• Origin: China
• HS Code: 28500090
• Production Capacity: 500 Tons/Year

Product Description

Sodium hydride [7646-69-7]

Identification
Name		Sodium hydride
Molecular Formula		NaH
Molecular Weight		24.00
CAS Registry Number		7646-69-7
EINECS		231-587-3

 

Properties
Density		1.2
Melting point		800 ºC (dec.)
Water solubility		REACTS

Sodium hydride is the chemical compound with the empirical formula NaH. This alkali metal hydride is primarily used as a strong yet combustible base in organic synthesis. NaH is representative of the saline hydrides, meaning it is a salt-like hydride, composed of Na⁺ and H⁻ ions, in contrast to the more molecular hydrides such as borane, methane, ammonia and water. It is an ionic material that is insoluble in organic solvents (although soluble in molten Na), consistent with the fact that H⁻ remains an unknown anion in solution. Because of the insolubility of NaH, all reactions involving NaH occur at the surface of the solid.

Applications in organic synthesis

As a strong base

NaH is a base of wide scope and utility in organic chemistry.As a superbase, it is capable of deprotonating a range of even weak Brønsted acids to give the corresponding sodium derivatives. Typical "easy" substrates contain O-H, N-H, S-H bonds, including alcohols, phenols, pyrazoles, and thiols.

NaH notably deprotonates carbon acids (i.e., C-H bonds) such as 1,3-dicarbonyls such as malonic esters. The resulting sodium derivatives can be alkylated. NaH is widely used to promote condensation reactions of carbonyl compounds via the Dieckmann condensation, Stobbe condensation, Darzens condensation, and Claisen condensation. Other carbon acids susceptible to deprotonation by NaH include sulfonium salts and DMSO. NaH is used to make sulfur ylides, which in turn are used to convert ketones into epoxides, as in the Johnson-Corey-Chaykovsky reaction.

As a reducing agent

NaH reduces certain main group compounds, but analogous reactivity is very rare in organic chemistry (see below).^[11] Notably boron trifluoride reacts to give diborane and sodium fluoride:

6 NaH + 2 BF₃ → B₂H₆ + 6 NaF

Si-Si and S-S bonds in disilanes and disulfides are also reduced.

A series of reduction reactions, including the hydrodecyanation of tertiary nitriles, reduction of imines to amines, and amides to aldehydes, can be effected by a composite reagent composed of sodium hydride and an alkali metal iodide (NaH:MI, M = Li, Na).

Hydrogen storage

Although not commercially significant sodium hydride has been proposed for hydrogen storage for use in fuel cell vehicles. In one experimental implementation, plastic pellets containing NaH are crushed in the presence of water to release the hydrogen. One challenge with this technology is the regeneration of NaH from the NaOH.

Practical considerations

Sodium hydride is sold usually as a mixture of 60% sodium hydride (w/w) in mineral oil. Such a dispersion is safer to handle and weigh than pure NaH. The compound is often used in this form but the pure grey solid can be prepared by rinsing the oil with pentane or THF, with care being taken because the washings will contain traces of NaH that can ignite in air. Reactions involving NaH require air-free techniques. Typically NaH is used as a suspension in THF, a solvent that resists deprotonation but solvates many organosodium compounds.

Safety

NaH can ignite in air, especially upon contact with water to release hydrogen, which is also flammable. Hydrolysis converts NaH into sodium hydroxide (NaOH), a caustic base. In practice, most sodium hydride is dispensed as a dispersion in oil, which can be safely handled in air.